[1]余慧群 余 意.饮用水中有机物及其净化技术研究进展[J].大众科技,2019,21(02):7-13.
 Research Progress of Organic Pollutants in Drinking Water and Their Purification Technology[J].Popular Science & Technology,2019,21(02):7-13.





Research Progress of Organic Pollutants in Drinking Water and Their Purification Technology
余慧群12 余 意34
(1.中国科技开发院广西分院,广西 南宁 530001;2.广西科技经济开发中心,广西 南宁 530001;3.南宁市桂润环境工程有限公司,广西 南宁 530001; 4.广西桂润环保科技有限公司,广西 南宁 530001)
drinking water organic pollutants removal technology research progress
饮用水中的有机污染物是影响人体健康的重要因素。文章将饮用水中的有机物按其性质的不同划分为天然有机物(NOM)、消毒副产物(DBPs)和新型有机物(ECs)3 大类进行起源与危害介绍,并对混凝、吸附、膜过滤、AOPs(高级氧化工艺)以及离子交换等水中有机物的去除净化技术的应用现状和处理效果进行了归纳和总结。
The organic pollutants in drinking water are important factors affecting human health. In this paper, the organic substances in drinking water are classified into natural organic matters (NOM), disinfection by-products (DBPs) and emerging organic compounds (ECs) according to their different properties. The origins and hazards of them are introduced. The application status and treatment effect on the removal and purification technologies of organic substances in water, such as flocculation, adsorption, membrane filtration, AOPs (advanced oxidation process) and ion exchange are summarized and discussed in detail.


【参考文献】 [1] 苗硕.中国淡水资源现状与保护措施探讨[J].现代商贸工业,2010(17):19-21. [2] 中华人民共和国环境保护部.2016 年中国环境状况公报[R].北京:中华人民共和国环境保护部,2016. [3] 岳舜琳.给水中有机物与Ames 致突物的相关性[J].中国给水排水,2003,19(1):20-22. [4] 叶立群.强化混凝技术在去除给水原水中腐植酸中的应用[J].武汉理工大学学报,2001,25(2):180-183. [5] Hua G,Reckhow D A,Abusallout I.Correlation between SUVA and DBP formation during chlorination and chloramination of NOM fractions from different sources [J].Chemosphere,2015,130:82-89. [6] Villanueva C M,Cantor K P,Cordier S,et al.Disinfection byproducts and bladder cancer[J].Epidemiology,2004,15(3): 357-367. [7] Villanueva C M,Cantor K P,Grimalt J O,et al.Bladder cancer and eposure to water disinfection by-products through ingestion,bathing,showering,and swimming in pools[J]. American Journal of Epidemiology,2007,165(2):148-156. [8] Amrita Pal,Yiliang He,Martin Jekel,et al.Emerging contaminants of public health significance as water quality indicator compounds in the urban water cycle[J].Environment International,2014,71:46-62. [9] Gunnarsson L,Adolfsson-Erici M,Bj?rlenius B,et al.Comparison of six different sewage treatment processes-reduction of estrogenic substances and effects on gene expression in exposed male fish[J].Science of the Total Environment,2009, 407(19):5235-5242. [10] Hernando M D,Petrovic M,Fernández-Alba A R,et al. Analysis by liquid chromatography–electrospray ionization tandem mass spectrometry and acute toxicity evaluation for β-blockers and lipid-regulating agents in wastewater sample [J].Journal of Chromatography A,2004,1046(1-2):133-140. [11] Hernando M D,Mezcua M,Fernández-Alba A R,et al. Environmental risk assessment of pharmaceutical residues in wastewater effluents,surface waters and sediments[J]. Talanta,2006,69(2):334-342. [12] Wang Z,Zhang X H,Huang Y,et al.Comprehensive evaluation of pharmaceuticals and personal care products (PPCPs) in typical highly urbanized regions across China[J].Environmental Pollution,2015,204:223-232. [13] Luo Y L,Guo W S,Ngo H H,et al.A review on the occurrence of micropollutants in the aquatic environment and their fate and removal during wastewater treatment[J].Science of the Total Environment,2014,473:619-641. [14] Peng X,Ou W,Wang C,et al.Occurrence and ecological - 12 - potential of pharmaceuticals and personal care products in groundwater and reservoirs in the vicinity of municipal landfills in Chinai[J].Science of the Total Environ,2014, 490:889-898. [15] Loos R,Locoro G,Comero S,et al.Pan-European survey on the occurrence of selected polar organic persistent pollutants in ground water[J].Water Research,2010,44 (14):4115-4126. [16] Mergen M R D,Jefferson B,Parsons S A,et al.Magnetic ion- exchange resin treatment:impact of water type and resin use[J].Water Research,2008,42:1977-1988. [17] Zhou J,Chang Q,Wang Y,et al.Separation of stable oil–water emulsion by the hydrophilic nano-sized ZrO2 modified Al2O3 microfiltration membrane[J].Separation and Purification Technology,2010,75:243-248. [18] Lu N C,Liu J C.Removal of phosphate and fluoride from wastewater by a hybrid precipitation-microfiltration process [J].Separation and Purification Technology,2010,74:329-335. [19] 汪燕.饮用水处理中超滤膜污染及清洗方法的中试研究[D].北京:北京建筑工程学院,2010. [20] 李圭白,杨艳玲.超滤—第三代城市饮用水净化工艺的核心技术[J].供水技术,2007,1(1):1-3. [21] Kim H C,Hong J H,Lee S.Fouling of microfiltration membranes by natural organic matter after coagulation treatment:A comparison of different initial mixing conditions [J].Journal of Membrane Science,2006,283(1-2):266-272. [22] Heo J,Flora J R V,Her N,et al.Removal of bisphenol A and 17-βestradiol in single walled carbon nanotubes-ultrafiltration (SWNTs-UF) membrane systems[J].Separation and Purification Technology,2012,90:39-52. [23] Melo-Guimar?es A,Torner-Morales F J,Durán-álvarez Juan C,et al.Removal and fate of emerging contaminants combining biological,flocculation and membrane treatments[J].Water Science & Technology,2013,67(4):877-885. [24] Mccloskey B P,Park T H K B,Ju H,et al.Influence of polydopamine deposition conditions on pure water flux and foulant adhesion resistance of reverse osmosis,ultrafiltration, and microfiltration membranes[J].Polymer (Guildf),2010,51: 3472-3485. [25] Sutzkover-Gutman I,Hasson D,Semiat R.Humic substances fouling in ultrafiltration processes[J].Desalination,2010,261 (3):218-231. [26] Han X,Liang C F,Li T Q,et al.Simultaneous removal of cadmium and sulfamethoxazole from aqueous solution by rice straw biochar[J].Journal of Zhejiang University Science B Biomedicine & Biotechnology,2013,14(7):640-649. [27] Vatanpour V,Madaeni S S,Moradian R,et al.Fabrication and characterization of novel antifouling nanofiltration membrane prepared from oxidized multiwalled carbon nanotube/polyethersulfone nanocomposite[J].Journal of Membrane Science,2011,375(1):284-294. [28] Acero J L,Benitez F J,Teva F,et al.Retention of emerging micropollutants from UP water and a municipal secondary effluent by ultrafiltration and nanofiltration[J].Chemical Engineering Journal,2010,163(3):264-272. [29] Dai C M,Geissen S U,Zhang Y L,et al.Performance evaluation and application of molecularly imprinted polymer for separation of carbamazepine in aqueous solution[J].Journal of Hazardous Materials,2010,184(1-3): 156-163. [30] Tang Y L,Guo H G,Xiao L,et al.Synthesis of reduced graphene oxide/magnetite composites and investigation of their adsorption performance of fluoroquinolone antibiotics [J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2013,424(17):74-80. [31] Ajmani G S,Goodwin D,Marsh K,et al.Modification of low pressure membranes with carbon nanotube layers for fouling control[J].Water Research,2012,46(17):5645-5654. [32] Wang S,Liang S,Liang P,et al.In-situ combined dual-layer CNT/PVDF membrane for electrically-enhanced fouling resistance[J].Journal of Membrane Science,2015,491:37-44. [33] Wang Y,Zhu J,Huang H,et al.Carbon nanotube composite membranes for microfiltration of pharmaceuticals and personal care products:Capabilities and potential mechanisms [J].Journal of Membrane Science,2015,479:165-174. [34] Engel M,Chefetz B.Adsorption and desorption of dissolved organic matter by carbon nanotubes:Effects of solution chemistry[J].Environmental Pollution,2016,213:90-98. [35] Wang Y,Huang H,Wei X.Influence of wastewater precoagulation on adsorptive filtration of pharmaceutical and personal care products by carbon nanotube membranes [J].Chemical Engineering Journal,2018,333(1):66-75. [36] Cho H H,Huang H,Schwab K.Effects of solution chemistry on the adsorption of ibuprofen and triclosan onto carbon nanotubes[J].Langmuir,2011,27(21):12960-12967. [37] Mohammadi A,Kazemipour M,Ranjbar H,et al.Amoxicillin removal from aqueous media using multi-walled carbon nanotubes[J].Fullerene Science and Technology,2015,23(2): 165-169. [38] Carabineiro S A C,Thavorn-Amornsri T,Pereira M F R, et al.Comparison between activated carbon,carbon xerogel and carbon nanotubes for the adsorption of the antibiotic ciprofloxacin[J].Catalysis Today,2012,186(1):29-34. [39] Ji L,Chen W,Bi J,et al.Adsorption of tetracycline on single-walled and multi-walled carbon nanotubes as affected by aqueous solution chemistry[J].Environmental toxicology and chemistry / SETAC,2010,29(12):2713-2719. [40] Peng H,Pan B,Wu M,et al.Adsorption of ofloxacin and norfloxacin on carbon nanotubes:Hydrophobicity-and structure-controlled process[J].Journal of Hazardous Materials, 2012,233-234:89-96. [41] Yang W,Lu Y,Zheng F,et al.Adsorption behavior and mechanisms of norfloxacin onto porous resins and carbon nanotube[J].Chemical Engineering Journal,2012,179:112-118. [42] Zhao Y X,Gao B Y,Zhang G Z,et al.Coagulation and sludge recovery using titanium tetrachloride as coagulant for real water treatment:a comparison against traditional aluminum and iron salts[J].Separation and Purification Technology, 2014,130:19-27. [43] Zhao Y X,Gao B Y,Shon H K,et al.Coagulation characteristics of titanium (Ti) salt coagulant compared with aluminum (Al) and iron (Fe) salts[J].Journal of Hazardous Materials,2011,185:1536-1542. [44] Jarvis P,Sharp E,Pidou M,et al.Comparison of coagulation performance and floc properties using a novel zirconium coagulant against traditional ferric and alum coagulants [J].Water Research,2012,46:4179-4187. - 13 - [45] Zhao Y X,Gao B Y,Shon H K,et al.Floc characteristics of titanium tetrachloride (TiCl4) compared with aluminum and iron salts in humic acidekaolin synthetic water treatment [J].Separation and Purification Technology,2011,81:332-338. [46] Wang S,Liu C,Li Q.Impact of polymer flocculants on coagulation microfiltration of surface water[J].Water Research, 2013,47:4538-4546. [47] Al-Wasify R S,Al-Sayed A A,Saleh S M,et al.Bacterial exopolysaccharides as new natural coagulants for surface water treatment[J].International Journal of Pharm Tech Research,2015,8(9):198-207. [48] Zhao S,Gao B,Wang Y,et al.Influence of a new coagulant aid-Enteromorpha extract on coagulation performance and floc characteristics of aluminum sulfate coagulant in kaolin-humic acid solution treatment[J].Colloids and Surfaces A Physicochemical and Engineering Aspects,2013, 417:161-169. [49] Mikko Veps?l?inen,Pulliainen M,Mika Sillanp??.Effect of electrochemical cell structure on natural organic matter (NOM) removal from surface water through electrocoagulation (EC)[J].Separation & Purification Technology,2012,99(41): 20-27. [50] Dubrawski K L,Mohseni M.Standardizing electrocoagulation reactor design:iron electrodes for NOM removal[J]. Chemosphere,2013,91:55-60. [51] Sarkar S,Ali S,Rehmann L,et al.Degradation of estrone in water and wastewater by various advanced oxidation processes[J].Journal of Hazardous Materials,2014,278:16-24. [52] Bolobajev J,Trapido M,Goi A.Effect of iron ion on doxycycline photocatalytic and Fenton-based autocatatalytic decomposition[J].Chemosphere,2016,153:220-226. [53] Souza F S,Liliana Amaral Féris.Degradation of caffeine by advanced oxidative processes:O3 and O3/UV[J].Ozone: Science & Engineering,2015,37(4):379-384. [54] Ramiro V R,Mario M T,Javier N L,et al.Assessment of the kinetics of oxidation of some steroids and pharmaceutical compounds in water using ozone[J].Journal of Environmental Chemical Engineering,2014,2(1):316-323. [55] Feng L,Watts M J,Yeh D,et al.The efficacy of ozone/BAC treatment on non-steroidal anti-inflammatory drug removal from drinking water and surface water[J].Ozone:Science & Engineering,2015,37(4):343-356. [56] Carra I,Sánchez Pérez,José Antonio,Malato S,et al.Application of high intensity UVC-LED for the removal of acetamiprid with the photo-Fenton process[J].Chemical Engineering Journal,2015,264:690-696. [57] Villegas-Guzman P,Silva-Agredo J,Giraldo-Aguirre A L, et al.Enhancement and inhibition effects of water matrices during the sonochemical degradation of the antibiotic dicloxacillin[J].Ultrasonics Sonochemistry,2015,22:211-219.


【收稿日期】2018-12-11 【基金项目】广西科技计划项目“低浓度有机废水的双膜内循环生物处理工艺研究与应用示范”(桂科攻AB16380277)。【作者简介】余慧群(1974-),女,湖北黄冈人,中国科技开发院广西分院高级工程师,从事科技管理与科技咨询工作。
更新日期/Last Update: 2019-03-25